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What are other names or identifying information for ammonia?

CAS Registry No.: 7664-41-7
Other Names: Anhydrous ammonia, Liquid ammonia
Main Uses: Used as a fertilizer, to make plastics, fibers and other chemicals, as a refrigerant, and in many other applications.
Appearance: Colourless gas.
Odour: Ammonia-like

Canadian TDG: UN1005


What is the WHMIS classification?

A - Compressed Gas; B1 - Flammable Gas; D1A - Very Toxic; E - Corrosive

Symbol for Class A
Class A
Symbol for Class B
Class B1
Symbol for Class D1
Class D1A
Symbol for Class E
Class E

What are the most important things to know about ammonia in an emergency?

Emergency Overview: Colourless gas. Ammonia-like odour. COMPRESSED GAS. Contains gas under pressure. May explode if heated. FLAMMABLE GAS. High concentrations can be a fire and explosion hazard, especially in confined spaces. Can decompose at high temperatures forming very flammable hydrogen gas. VERY TOXIC. Fatal if inhaled. Corrosive to the respiratory tract. CORROSIVE. Causes severe skin burns and eye damage. May cause frostbite.


What are the potential health effects of ammonia?

Main Routes of Exposure: Inhalation. Skin contact. Eye contact.

  • Inhalation: VERY TOXIC, can cause death. Can cause severe irritation of the nose and throat. Can cause life-threatening accumulation of fluid in the lungs (pulmonary edema). Symptoms may include coughing, shortness of breath, difficult breathing and tightness in the chest. Symptoms may develop hours after exposure and are made worse by physical effort. Long-term damage may result from a severe short-term exposure.
  • Skin Contact: CORROSIVE. The gas irritates or burns the skin. Permanent scarring can result. Direct contact with the liquefied gas can chill or freeze the skin (frostbite). Symptoms of more severe frostbite include a burning sensation and stiffness. The skin may become waxy white or yellow. Blistering, tissue death and infection may develop in severe cases.
  • Eye Contact: CORROSIVE. The gas irritates or burns the eyes. Permanent damage including blindness can result. Direct contact with the liquefied gas can freeze the eye. Permanent eye damage or blindness can result.
  • Ingestion: Not a relevant route of exposure (gas).
  • Effects of Long-Term (Chronic) Exposure: May harm the respiratory system. Can irritate and inflame the airways.
  • Carcinogenicity: Not known to cause cancer.

International Agency for Research on Cancer (IARC): Not specifically evaluated.
American Conference for Governmental Industrial Hygienists (ACGIH): Not specifically designated.

  • Teratogenicity / Embryotoxicity: Not known to harm the unborn child.
  • Reproductive Toxicity: Not known to be a reproductive hazard.
  • Mutagenicity: Not known to be a mutagen. Conclusions cannot be drawn from the limited studies available.

What are first aid measures for ammonia?

Inhalation: Take precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment). Move victim to fresh air. If breathing is difficult, trained personnel should administer emergency oxygen. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary edema may be delayed. Immediately call a Poison Centre or doctor. Treatment is urgently required. Transport to a hospital.

Skin Contact: Gas: flush with lukewarm, gently flowing water for 5 minutes. If irritation or pain persists, see a doctor. Liquefied gas: quickly remove victim from source of contamination. DO NOT attempt to rewarm the affected area on site. DO NOT rub area or apply direct heat. Gently remove clothing or jewelry that may restrict circulation. Carefully cut around clothing that sticks to the skin and remove the rest of the garment. Loosely cover the affected area with a sterile dressing. DO NOT allow victim to drink alcohol or smoke. Immediately call a Poison Centre or doctor. Treatment is urgently required. Transport to a hospital.

Eye Contact: Gas: immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open. If irritation or pain persists, see a doctor. Liquefied gas: move victim to fresh air. Immediately and briefly flush with lukewarm, gently flowing water. DO NOT attempt to rewarm. Cover both eyes with a sterile dressing. DO NOT allow victim to drink alcohol or smoke.

Ingestion: Not applicable (gas).

First Aid Comments: Some of the first aid procedures recommended here require advanced first aid training. All first aid procedures should be periodically reviewed by a doctor familiar with the chemical and its conditions of use in the workplace.


What are fire hazards and extinguishing media for ammonia?

Flammable Properties: FLAMMABLE GAS. High airborne concentrations can be ignited and pose a significant fire and explosion hazard, especially in a confined space. A large and intense energy source is necessary to ignite ammonia gas.

Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog.

Specific Hazards Arising from the Chemical: Heat from fire can cause a rapid build-up of pressure inside cylinders. Explosive rupture and a sudden release of large amounts of gas may result. Cylinder may rocket. In a fire, the following hazardous materials may be generated: flammable hydrogen.


What are the stability and reactivity hazards of ammonia?

  • Chemical Stability: Normally stable.
  • Conditions to Avoid: High temperatures. Open flames, sparks, static discharge, heat and other ignition sources. High energy sources, e.g. welding arcs.
  • Incompatible Materials: Increased risk of fire and explosion on contact with: oxidizing agents (e.g. peroxides), strong acids (e.g. hydrochloric acid), halogens (e.g. chlorine). Not corrosive to: carbon steel, aluminum alloys.
  • Hazardous Decomposition Products: Flammable hydrogen gas.
  • Possibility of Hazardous Reactions: None known.

What are accidental release measures for ammonia?

Personal Precautions: Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Use personal protective equipment as required. Eliminate ignition sources. Increase ventilation to area or move leaking container to a well-ventilated and secure area.

Methods for Containment and Clean-up: Knock down gas with fog or fine water spray. Do not direct water at spill or source. If possible, turn leaking container so that gas escapes rather than liquefied gas. Dike spilled product to prevent runoff.


What handling and storage practices should be used when working with ammonia?

Handling: Immediately report leaks, spills or failures of the safety equipment (e.g. ventilation system). In event of a spill or leak, immediately put on escape-type respirator and exit the area. Do NOT work alone with this product. Get medical attention for all exposures. Symptoms can be delayed. Prevent accidental contact with incompatible chemicals. Use corrosion-resistant tools and equipment. Eliminate heat and ignition sources such as sparks, open flames, hot surfaces and static discharge. Post "No Smoking" signs. Do not use near welding operations or other high energy sources. Do not weld, cut or perform hot work on empty container until all traces of product have been removed. Prevent heating. Use the pressure regulator appropriate for cylinder pressure and contents. Secure cylinder in an up-right position. Protect cylinders from damage. Use a suitable hand truck to move cylinders; do not drag, roll, slide, or drop. Keep containers tightly closed when not in use or empty.

Storage: Store in an area that is: cool, dry, out of direct sunlight and away from heat and ignition sources, separate from incompatible materials, secure and separate from work areas, an approved, fire-resistant area. Store in the original, labelled, shipping container. Always secure (e.g. chain) cylinders in an upright position to a wall, rack or other solid structure. Empty containers may contain hazardous residue. Store separately. Keep closed. Comply with all applicable health and safety regulations, fire and building codes.


What is the American Conference of Governmental Industrial Hygienists (ACGIH®) recommended exposure limit for ammonia?

ACGIH® TLV® - TWA: 25 ppm

ACGIH® TLV® - STEL [C]: 35 ppm

Exposure Guideline Comments: TLV® = Threshold Limit Value. TWA = Time-Weighted Average. STEL = Short-term Exposure Limit. C = Ceiling limit.


What are the engineering controls for ammonia?

Engineering Controls: Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air. It may be necessary to use stringent control measures such as process enclosure to prevent product release into the workplace. For large scale use of this product: use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product is used and stored. Use an automatic leak detection system. Exhaust directly to the outside, taking any necessary precautions for environmental protection. Provide eyewash and safety shower if contact or splash hazard exists.


What Personal Protective Equipment (PPE) is needed when working with ammonia?

Eye/Face Protection: Wear chemical safety goggles. A face shield (with safety goggles) may also be necessary.

Skin Protection: Wear chemical protective clothing e.g. gloves, aprons, boots. In some operations: wear a chemical protective, full-body encapsulating suit and self-contained breathing apparatus (SCBA). Suitable materials include: butyl rubber, Viton®, Viton®/butyl rubber, Trellchem® HPS, Trellchem® VPS, Tychem® Responder, Tychem® TK.

Respiratory Protection: Up to 250 ppm: wear a NIOSH approved air-purifying respirator with an appropriate cartridge, wear a NIOSH approved self-contained breathing apparatus (SCBA) or supplied air respirator. Up to 300 ppm: wear a NIOSH approved self-contained breathing apparatus (SCBA) or supplied air respirator. ESCAPE: wear a full facepiece NIOSH approved air-purifying respirator with a cartridge to protect against ammonia For non-routine or emergency situations: wear a NIOSH approved self-contained breathing apparatus (SCBA) or supplied air respirator.

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Document last updated on November 5, 2013

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