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CAS Registry No.: 7664-41-7
Other Names: Anhydrous ammonia, Liquid ammonia
Main Uses: Used as a fertilizer, to make plastics, fibers and other chemicals, as a refrigerant, and in many other applications.
Appearance: Colourless gas.
Canadian TDG: UN1005
A - Compressed Gas; B1 - Flammable Gas; D1A - Very Toxic; E - Corrosive
Emergency Overview: Colourless gas. Ammonia-like odour. COMPRESSED GAS. Contains gas under pressure. May explode if heated. FLAMMABLE GAS. High concentrations can be a fire and explosion hazard, especially in confined spaces. Can decompose at high temperatures forming very flammable hydrogen gas. VERY TOXIC. Fatal if inhaled. Corrosive to the respiratory tract. CORROSIVE. Causes severe skin burns and eye damage. May cause frostbite.
Main Routes of Exposure: Inhalation. Skin contact. Eye contact.
International Agency for Research on Cancer (IARC): Not specifically evaluated.
American Conference for Governmental Industrial Hygienists (ACGIH): Not specifically designated.
Inhalation: Take precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment). Move victim to fresh air. If breathing is difficult, trained personnel should administer emergency oxygen. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary edema may be delayed. Immediately call a Poison Centre or doctor. Treatment is urgently required. Transport to a hospital.
Skin Contact: Gas: flush with lukewarm, gently flowing water for 5 minutes. If irritation or pain persists, see a doctor. Liquefied gas: quickly remove victim from source of contamination. DO NOT attempt to rewarm the affected area on site. DO NOT rub area or apply direct heat. Gently remove clothing or jewelry that may restrict circulation. Carefully cut around clothing that sticks to the skin and remove the rest of the garment. Loosely cover the affected area with a sterile dressing. DO NOT allow victim to drink alcohol or smoke. Immediately call a Poison Centre or doctor. Treatment is urgently required. Transport to a hospital.
Eye Contact: Gas: immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open. If irritation or pain persists, see a doctor. Liquefied gas: move victim to fresh air. Immediately and briefly flush with lukewarm, gently flowing water. DO NOT attempt to rewarm. Cover both eyes with a sterile dressing. DO NOT allow victim to drink alcohol or smoke.
Ingestion: Not applicable (gas).
First Aid Comments: Some of the first aid procedures recommended here require advanced first aid training. All first aid procedures should be periodically reviewed by a doctor familiar with the chemical and its conditions of use in the workplace.
Flammable Properties: FLAMMABLE GAS. High airborne concentrations can be ignited and pose a significant fire and explosion hazard, especially in a confined space. A large and intense energy source is necessary to ignite ammonia gas.
Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog.
Specific Hazards Arising from the Chemical: Heat from fire can cause a rapid build-up of pressure inside cylinders. Explosive rupture and a sudden release of large amounts of gas may result. Cylinder may rocket. In a fire, the following hazardous materials may be generated: flammable hydrogen.
Personal Precautions: Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Use personal protective equipment as required. Eliminate ignition sources. Increase ventilation to area or move leaking container to a well-ventilated and secure area.
Methods for Containment and Clean-up: Knock down gas with fog or fine water spray. Do not direct water at spill or source. If possible, turn leaking container so that gas escapes rather than liquefied gas. Dike spilled product to prevent runoff.
Handling: Immediately report leaks, spills or failures of the safety equipment (e.g. ventilation system). In event of a spill or leak, immediately put on escape-type respirator and exit the area. Do NOT work alone with this product. Get medical attention for all exposures. Symptoms can be delayed. Prevent accidental contact with incompatible chemicals. Use corrosion-resistant tools and equipment. Eliminate heat and ignition sources such as sparks, open flames, hot surfaces and static discharge. Post "No Smoking" signs. Do not use near welding operations or other high energy sources. Do not weld, cut or perform hot work on empty container until all traces of product have been removed. Prevent heating. Use the pressure regulator appropriate for cylinder pressure and contents. Secure cylinder in an up-right position. Protect cylinders from damage. Use a suitable hand truck to move cylinders; do not drag, roll, slide, or drop. Keep containers tightly closed when not in use or empty.
Storage: Store in an area that is: cool, dry, out of direct sunlight and away from heat and ignition sources, separate from incompatible materials, secure and separate from work areas, an approved, fire-resistant area. Store in the original, labelled, shipping container. Always secure (e.g. chain) cylinders in an upright position to a wall, rack or other solid structure. Empty containers may contain hazardous residue. Store separately. Keep closed. Comply with all applicable health and safety regulations, fire and building codes.
ACGIH® TLV® - TWA: 25 ppm
ACGIH® TLV® - STEL [C]: 35 ppm
Exposure Guideline Comments: TLV® = Threshold Limit Value. TWA = Time-Weighted Average. STEL = Short-term Exposure Limit. C = Ceiling limit.
NOTE: In many (but not all) Canadian jurisdictions, the exposure limits are similar to the ACGIH® TLVs®. Since legislation varies by jurisdiction, contact your local jurisdiction for exact details. A list is available in the OSH Answers on Canadian Governmental Occupational Health & Safety Departments.
A list of which acts and regulations that cover exposure limits to chemical and biological agents is available on our website. Please note that while you can see the list of legislation for free, you will need a subscription to view the actual documentation.
Engineering Controls: Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air. It may be necessary to use stringent control measures such as process enclosure to prevent product release into the workplace. For large scale use of this product: use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product is used and stored. Use an automatic leak detection system. Exhaust directly to the outside, taking any necessary precautions for environmental protection. Provide eyewash and safety shower if contact or splash hazard exists.
Eye/Face Protection: Wear chemical safety goggles. A face shield (with safety goggles) may also be necessary.
Skin Protection: Wear chemical protective clothing e.g. gloves, aprons, boots. In some operations: wear a chemical protective, full-body encapsulating suit and self-contained breathing apparatus (SCBA). Suitable materials include: butyl rubber, Viton®, Viton®/butyl rubber, Trellchem® HPS, Trellchem® VPS, Tychem® TK.
Up to 250 ppm:
(APF = 10) Any chemical cartridge respirator with cartridge(s) providing protection against ammonia*; or Any supplied-air respirator*.
*Reported to cause eye irritation or damage; may require eye protection.
APF = Assigned Protection Factor
Recommendations apply only to National Institute for Occupational Safety and Health (NIOSH) approved respirators. Refer to the NIOSH Pocket Guide to Chemical Hazards for more information.