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CAS Registry No.: 7782-50-5
Other Names: Liquefied chlorine gas, Chlorine gas
Main Uses: Manufacture of other chemicals, bleaching agent, water purification.
Appearance: Green - yellow gas. Clear yellow or amber liquid (under pressure).
Canadian TDG: UN1017
A - Compressed Gas; D1A - Very Toxic; E - Corrosive
Emergency Overview: Green - yellow gas. Pungent odour. Will not burn. COMPRESSED GAS. Contains gas under pressure. May explode if heated. OXIDIZER. May cause or intensify fire. Highly Reactive. Incompatible with many common chemicals. VERY TOXIC. Fatal if inhaled. Corrosive to the respiratory tract. A severe, short-term exposure may cause long-term respiratory effects (e.g., Reactive Airways Dysfunction (RADS)). CORROSIVE. Causes severe skin burns and eye damage. May cause frostbite.
Emergency Overview: Inhalation. Skin contact. Eye contact.
International Agency for Research on Cancer (IARC): Not specifically evaluated.
American Conference for Governmental Industrial Hygienists (ACGIH): A4 - Not classifiable as a human carcinogen.
Inhalation: Take precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment). Move victim to fresh air. Keep at rest in a position comfortable for breathing. If breathing is difficult, trained personnel should administer emergency oxygen. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary edema may be delayed. Immediately call a Poison Centre or doctor. Treatment is urgently required. Transport to a hospital.
Skin Contact: Gas: Flush with lukewarm, gently flowing water for 5 minutes. If irritation or pain persists, see a doctor. Liquefied gas: quickly remove victim from source of contamination. DO NOT attempt to rewarm the affected area on site. DO NOT rub area or apply direct heat. Gently remove clothing or jewelry that may restrict circulation. Carefully cut around clothing that sticks to the skin and remove the rest of the garment. Loosely cover the affected area with a sterile dressing. DO NOT allow victim to drink alcohol or smoke. Immediately call a Poison Centre or doctor. Treatment is urgently required. Transport to a hospital.
Eye Contact: Gas: immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open. If irritation or pain persists, see a doctor. Liquefied gas: avoid direct contact. Wear chemical protective gloves if necessary. Immediately and briefly flush with lukewarm, gently flowing water. DO NOT attempt to rewarm. Cover both eyes with a sterile dressing. DO NOT allow victim to drink alcohol or smoke. Immediately call a Poison Centre or doctor. Treatment is urgently required. Transport to a hospital.
Ingestion: Not applicable (gas).
First Aid Comments: All first aid procedures should be periodically reviewed by a doctor familiar with the chemical and its conditions of use in the workplace.
Inhalation: Does not burn. Strong OXIDIZER. May intensify fire.
Suitable Extinguishing Media: Not combustible. Use extinguishing agent suitable for surrounding fire.
Specific Hazards Arising from the Chemical: Heat from fire can cause a rapid build-up of pressure inside cylinders. Explosive rupture and a sudden release of large amounts of gas may result. Cylinder may rocket. In a fire, the following hazardous materials may be generated: corrosive hydrogen chloride.
Personal Precautions: Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Vapour or gas may accumulate in hazardous amounts in low-lying areas especially inside confined spaces, if ventilation is not sufficient. Remove or isolate incompatible materials as well as other hazardous materials.
Methods for Containment and Clean-up: Small spills or leaks: stop or reduce leak if safe to do so. Ventilate the area to prevent the gas from accumulating, especially in confined spaces. Large spills or leaks: stop or reduce leak if safe to do so. Ventilate the area to prevent the gas from accumulating, especially in confined spaces. If possible, turn leaking container so that gas escapes rather than liquefied gas. Knock down gas with fog or fine water spray. Do not direct water at spill or source.
Other Information: Contact supplier, local fire and emergency services for help.
Handling: In event of a spill or leak, immediately put on escape-type respirator and exit the area. Immediately report leaks, spills or failures of the safety equipment (e.g. ventilation system). Secure cylinder in an up-right position. Protect cylinders from damage. Use a suitable hand truck to move cylinders; do not drag, roll, slide, or drop. Use the pressure regulator appropriate for cylinder pressure and contents.
Storage: Store in an area that is: cool, dry, well-ventilated, out of direct sunlight and away from heat and ignition sources, secure and separate from work areas, separate from incompatible materials, on the ground floor or preferably, in an isolated, detached building. Always secure (e.g. chain) cylinders in an upright position to a wall, rack or other solid structure. Label container with date received, date opened and disposal date. Use a first-in, first-out inventory system. Empty containers may contain hazardous residue. Store separately. Keep closed. Comply with all applicable health and safety regulations, fire and building codes.
ACGIH® TLV® - TWA : 0.5 ppm A4
ACGIH® TLV® - STEL [C]: 1 ppm
Exposure Guideline Comments: TLV® = Threshold Limit Value. TWA = Time-Weighted Average. STEL = Short-term exposure Limit. C = Ceiling limit. A4 = Not classifiable as a human carcinogen.
NOTE: In many (but not all) Canadian jurisdictions, the exposure limits are similar to the ACGIH® TLVs®. Since legislation varies by jurisdiction, contact your local jurisdiction for exact details. A list is available in the OSH Answers on Canadian Governmental Occupational Health & Safety Departments.
A list of which acts and regulations that cover exposure limits to chemical and biological agents is available on our website. Please note that while you can see the list of legislation for free, you will need a subscription to view the actual documentation.
Engineering Controls: Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air. Consider using Use a corrosion-resistant exhaust ventilation system separate from other ventilation systems. It may be necessary to use stringent control measures such as process enclosure to prevent product release into the workplace. Use backup controls (e.g. double mechanical pump seals) to prevent the release of this material due to equipment failure. Provide eyewash and safety shower if contact or splash hazard exists.
Eye/Face Protection: Wear chemical safety goggles. A face shield (with safety goggles) may also be necessary.
Skin Protection: Wear chemical protective clothing e.g. gloves, aprons, boots. Coveralls or long sleeve shirts and pants in some operations. Wear a chemical protective, full-body encapsulating suit and self-contained breathing apparatus (SCBA). Suitable materials include: butyl rubber, neoprene rubber, Viton®, Viton®/butyl rubber, Barrier® - PE/PA/PE, Silver Shield® - PE/EVAL/PE, Trellchem® HPS, Trellchem® VPS, Saranex®™, Tychem® BR/LV, Tychem® Responder® CSM, Tychem® TK. The following materials should NOT be used: natural rubber, polyvinyl chloride. Recommendations are NOT valid for very thin neoprene rubber gloves (0.3 mm or less).
Up to 5 ppm:
(APF = 10) Any chemical cartridge respirator with cartridge(s) providing protection against chlorine*; or Any supplied-air respirator*.
*Reported to cause eye irritation or damage; may require eye protection.
APF = Assigned Protection Factor
Recommendations apply only to National Institute for Occupational Safety and Health (NIOSH) approved respirators. Refer to the NIOSH Pocket Guide to Chemical Hazards for more information.